Title : Three-Coordinate Copper(II) Alkynyl Complex in C-C Bond Formation: The Sesquicentennial of the Glaser Coupling.

Pub. Date : 2020 Oct 28

PMID : 32956589






2 Functional Relationships(s)
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Compound Name
Protein Name
Organism
1 Radical capture represents the key Csp-Csp3 bond forming step in the copper catalyzed C-H functionalization of benzylic substrates R-H with alkynes H-C CR" (R" = (hetero)aryl, silyl) that provide Csp-Csp3 coupled products R-C CR via radical relay with tBuOOtBu as oxidant. tert-butyl peroxide DnaJ heat shock protein family (Hsp40) member C5 Homo sapiens
2 Radical capture represents the key Csp-Csp3 bond forming step in the copper catalyzed C-H functionalization of benzylic substrates R-H with alkynes H-C CR" (R" = (hetero)aryl, silyl) that provide Csp-Csp3 coupled products R-C CR via radical relay with tBuOOtBu as oxidant. tert-butyl peroxide DnaJ heat shock protein family (Hsp40) member C5 Homo sapiens