Title : Catalytic Chemoselective Sulfimidation with an Electrophilic [CoIII (TAML)]- -Nitrene Radical Complex*.

Pub. Date : 2021 Jan 4

PMID : 32810326






1 Functional Relationships(s)
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1 The cobalt species PPh 4 [Co III (TAML red )] is a competent and stable catalyst for the sulfimidation of (aryl)(alkyl)-substituted sulfides with iminoiodinanes reaching turnover numbers up to 900 and turnover frequencies of 640 min -1 under mild and aerobic conditions. Cobalt mitochondrially encoded cytochrome c oxidase III Homo sapiens