Title : More efficient spin-orbit coupling: adjusting the ligand field strength to the second metal ion in asymmetric binuclear platinum(ii) configurations.

Pub. Date : 2020 Jul 7

PMID : 32555914






1 Functional Relationships(s)
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1 Pt-1 showed an enhanced spin-orbit coupling (SOC), caused by the additional metal component through direct orbital hybridization at higher states, where the fixed molecular skeleton induced by the additional metal-ligand bonding also helped to suppress molecular distortion in the excited state, ensuring a high quantum yield (Phi, 0.89 in toluene), which is among the best results in bimetallic complexes. Platinum spindlin 1 Homo sapiens