Title : Electrocatalytic Proton Reduction by a Cobalt Complex Containing a Proton-Responsive Bis(alkylimdazole)methane Ligand: Involvement of a C-H Bond in H2 Formation.

Pub. Date : 2020 Oct 1

PMID : 32350932






1 Functional Relationships(s)
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1 Mechanistic investigations supported by Density Functional Theory (BP86) reveal that dihydrogen formation takes place in an intramolecular fashion through the participation of a methylene C-H bond of the HBMIM Ph2 ligand and a Co II -H bond through formal heterolytic splitting of the latter. Hydrogen mitochondrially encoded cytochrome c oxidase II Homo sapiens