Title : A Remote 'Imidazole'-Based Ruthenium(II) Para-Cymene Pre-catalyst for the Selective Oxidation Reaction of Alkyl Arenes and Alcohols.

Pub. Date : 2020 Mar 16

PMID : 32031753






2 Functional Relationships(s)
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1 Herein we disclosed the utilization of remote "imidazole" based precatalyst [( para -cymene)Ru II (L)Cl] + , C-1 where L = 2-(4-substituted-phenyl)-1H-imidazo[4,5-f][1,10] phenanthroline) for the selective oxidation of variety of alkyl arenes/heteroarenes and alcohols to their corresponding aldehydes or ketones in presence of tert -butyl hydroperoxide (TBHP). Ketones heterogeneous nuclear ribonucleoprotein C Homo sapiens
2 The substrate scope for C-1 promoted oxidation reaction was also assessed for the selective oxidation of 27-different alkyl arenes/heteroarenes and 25 different alcohols to their corresponding aldehydes/ketones with moderate to good yields. Ketones heterogeneous nuclear ribonucleoprotein C Homo sapiens