Title : Towards the Molecular Design of Spin-Crossover Complexes of 2,6-Bis(pyrazol-3-yl)pyridines.

Pub. Date : 2020 May 4

PMID : 31967374






2 Functional Relationships(s)
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1 Here we report the first N,N"-disubstituted 2,6-bis(pyrazol-3-yl)pyridines (3-bpp) that, against the common wisdom, induce a spin-crossover in otherwise high-spin iron(II) complexes by increasing the steric demand of a bulky substituent, an ortho-functionalized phenyl group. Iron spindlin 1 Homo sapiens
2 Here we report the first N,N"-disubstituted 2,6-bis(pyrazol-3-yl)pyridines (3-bpp) that, against the common wisdom, induce a spin-crossover in otherwise high-spin iron(II) complexes by increasing the steric demand of a bulky substituent, an ortho-functionalized phenyl group. Iron spindlin 1 Homo sapiens