Title : Various Anderson-type polyoxometalate-based metal-organic complexes induced by diverse solvents: assembly, structures and selective adsorption for organic dyes.

Pub. Date : 2020 Jan 28

PMID : 31904036






1 Functional Relationships(s)
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1 Six new Anderson-type polyoxometalate (POM)-based metal-organic complexes (MOCs), namely, {HCu(HPCAP)2[CrMo6(OH)6O18]} 2H2O (1), {Zn4(PCAP)2[CrMo6(OH)6O18]2(H2O)12} 4H2O (2), {Zn3(PCAP)2[CrMo6(OH)5O19](H2O)6} 6H2O (3), {Ni3(PCAP)2[NiMo6(OH)5O19](H2O)6} 8H2O (4), {Cu3(PCAP)2[AlMo6(OH)5O19](H2O)6} 6H2O (5), and {Co3(HPCAP)2[AlMo6(OH)6O18](H2O)10}[AlMo6(OH)6O18] 6H2O (6) (HPCAP = 3-(2-pyridinecarboxylic acid amido)pyridine), were constructed from diverse metal ions (CuII/ZnII/NiII/CoII), the HPCAP ligand and various Anderson-type POM anions under hydrothermal and solvothermal conditions and structurally characterized by single-crystal X-ray diffraction, IR spectroscopy, powder X-ray diffraction (PXRD) and thermogravimetric analyses (TGA). polyoxometalate I T-box transcription factor 1 Homo sapiens