Title : Bi- and tridentate stannylphosphines and their coordination to low-valent platinum.

Pub. Date : 2019 Nov 14

PMID : 31552976






1 Functional Relationships(s)
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Protein Name
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1 1 and 2 reacted with stoichiometric amounts of tristriphenylphosphine platinum(0) [Pt(PPh3)3] under toluene refluxing conditions leading to formation of Pt(ii) distorted square-planar complexes [Ph2P(o-C6H4CH2)Pt(SnR3)(PPh3)], (R = Ph, 4; R = Me, 5), each bearing a five-membered carbometallated ring resulting from Pt coordination to P and the benzylic C sp3 atom of the ligand architecture rather than from activation of the terminal Sn-C carbon bonds of the phenyl or methyl substituents which would have rendered six-membered rings. Toluene protein phosphatase 4 catalytic subunit Homo sapiens