Title : An alternative method for the synthesis of 2'-halogeno-1',2'-unsaturated uridine derivatives through syn-elimination of pivalic acid of 2'-halogeno- 2'-deoxy-1'-pivaloyloxyuracil nucleoside: preparation of its 2'-C-branched nucleosides.

Pub. Date : 2020

PMID : 31429364






1 Functional Relationships(s)
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1 The protocol was on the basis of the syn-elimination of pivalic acid from 2"-bromo-(7a,b) and 2"-iodo-(9a,b) 1"-pivaloyloxy-2"-deoxyuridine derivatives, which were derived from the halo-pivaloyloxylation of 3",5"-bis-O-TBDMS-1",2"-unsaturated uridine 1. 2"-bromo-(7a synemin Homo sapiens