Title : Exploration of a Chiral Cobalt Catalyst for Visible-Light-Induced Enantioselective Radical Conjugate Addition.

Pub. Date : 2019 Sep 16

PMID : 31293048






1 Functional Relationships(s)
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1 One well-defined chiral CoII -complex is shown to be an efficient catalyst in the visible-light-induced conjugated addition of enones by alkyl and acyl radicals, providing synthetically valued chiral ketones and 1,4-dicarbonyls in 47->99 % yields with up to 97:3 e.r. enones mitochondrially encoded cytochrome c oxidase II Homo sapiens