Title : Reaction of Indole Carboxylic Acid/Amide with Propargyl Alcohols: [4 + 3]-Annulation, Unexpected 3- to 2- Carboxylate/Amide Migration, and Decarboxylative Cyclization.

Pub. Date : 2019 Jul 19

PMID : 31246037






1 Functional Relationships(s)
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1 In contrast, indole-2-carboxylic acids/amides form fused seven-membered lactones/lactams (oxepinoindolones/azepinoindolones) upon treatment with substituted propargyl alcohols using catalytic Cu(OTf)2. propargyl alcohol POU class 2 homeobox 2 Homo sapiens