Title : From Phosphidic to Phosphonium? Umpolung of the P4 -Bonding Situation in [CpFe(CO)(L)(η1 -P4 )]+ Cations (L=CO or PPh3 ).

Pub. Date : 2019 Aug 9

PMID : 31066932






1 Functional Relationships(s)
Download
Sentence
Compound Name
Protein Name
Organism
1 Upon coordinating P4 to electron poor cyclopentadienyl-iron cations, the average P-P bond distances shrink and the respective P4 breathing mode in the Raman spectra (600 cm-1 , P4, free ) is blueshifted by >40 cm-1 in [CpFe(CO)(L)(eta1 -P4 )]+ cations (L=CO or PPh3 ). Iron protein phosphatase 4 catalytic subunit Homo sapiens