Title : Stereoselective Tandem Synthesis of syn-1,3-Diol Derivatives by Integrating Olefin Cross-Metathesis, Hemiacetalization, and Intramolecular Oxa-Michael Addition.

Pub. Date : 2019 May 17

PMID : 31045379






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1 Stereoselective tandem synthesis of syn-1,3-diol motifs, abundantly present in polyketide natural products and relevant pharmaceuticals, was achieved from homoallylic alcohols, alpha,beta-unsaturated ketones, and aldehydes. Polyketides synapsin I Homo sapiens