Title : Investigations on non-classical silylium ions leading to a cyclobutenyl cation.

Pub. Date : 2019 Mar 7

PMID : 30997003






6 Functional Relationships(s)
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1 Yet, from the reaction of 2-butyne with ion-like Me3Si-F-Al(ORF)3 (RF = C(CF3)3) the salt of the silylated tetramethyl cyclobutenyl cation [Me4C4-SiMe3]+[al-f-al]- 1 ([al-f-al]- = [(RFO)3Al-F-Al(ORF)3]-) was obtained in good yield (NMR, scXRD, Raman, and IR). al-f-al ankyrin repeat, SAM and basic leucine zipper domain containing 1 Homo sapiens
2 Yet, from the reaction of 2-butyne with ion-like Me3Si-F-Al(ORF)3 (RF = C(CF3)3) the salt of the silylated tetramethyl cyclobutenyl cation [Me4C4-SiMe3]+[al-f-al]- 1 ([al-f-al]- = [(RFO)3Al-F-Al(ORF)3]-) was obtained in good yield (NMR, scXRD, Raman, and IR). al-f-al ankyrin repeat, SAM and basic leucine zipper domain containing 1 Homo sapiens
3 Yet, from the reaction of 2-butyne with ion-like Me3Si-F-Al(ORF)3 (RF = C(CF3)3) the salt of the silylated tetramethyl cyclobutenyl cation [Me4C4-SiMe3]+[al-f-al]- 1 ([al-f-al]- = [(RFO)3Al-F-Al(ORF)3]-) was obtained in good yield (NMR, scXRD, Raman, and IR). al-f-al ankyrin repeat, SAM and basic leucine zipper domain containing 1 Homo sapiens
4 Yet, from the reaction of 2-butyne with ion-like Me3Si-F-Al(ORF)3 (RF = C(CF3)3) the salt of the silylated tetramethyl cyclobutenyl cation [Me4C4-SiMe3]+[al-f-al]- 1 ([al-f-al]- = [(RFO)3Al-F-Al(ORF)3]-) was obtained in good yield (NMR, scXRD, Raman, and IR). al-f-al ankyrin repeat, SAM and basic leucine zipper domain containing 1 Homo sapiens
5 By the addition of Et2O to a solution of 1, the [F-Al(ORF)3]- anion (and Et2O-Al(ORF)3) was generated from the [al-f-al]- counterion. al-f-al ankyrin repeat, SAM and basic leucine zipper domain containing 1 Homo sapiens
6 By the addition of Et2O to a solution of 1, the [F-Al(ORF)3]- anion (and Et2O-Al(ORF)3) was generated from the [al-f-al]- counterion. al-f-al ankyrin repeat, SAM and basic leucine zipper domain containing 1 Homo sapiens