Title : Solution and Solid State Properties for Low-Spin Cobalt(II) Dibenzotetramethyltetraaza[14]annulene [(tmtaa)CoII] and the Monopyridine Complex.

Pub. Date : 2019 Jan 22

PMID : 30618250






3 Functional Relationships(s)
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1 Toluene solutions of (tmtaa)CoII have 1H nuclear magnetic resonance (NMR) paramagnetic shifts, a solution-phase magnetic moment mueff (295 K) of 2.1 muB, and toluene glass electron paramagnetic resonance spectra that are most consistent with a low-spin ( S = 1/2) CoII with the unpaired electron located in the d yz orbital. Toluene mitochondrially encoded cytochrome c oxidase II Homo sapiens
2 Toluene solutions of (tmtaa)CoII have 1H nuclear magnetic resonance (NMR) paramagnetic shifts, a solution-phase magnetic moment mueff (295 K) of 2.1 muB, and toluene glass electron paramagnetic resonance spectra that are most consistent with a low-spin ( S = 1/2) CoII with the unpaired electron located in the d yz orbital. Toluene mitochondrially encoded cytochrome c oxidase II Homo sapiens
3 Toluene solutions of (tmtaa)CoII have 1H nuclear magnetic resonance (NMR) paramagnetic shifts, a solution-phase magnetic moment mueff (295 K) of 2.1 muB, and toluene glass electron paramagnetic resonance spectra that are most consistent with a low-spin ( S = 1/2) CoII with the unpaired electron located in the d yz orbital. Toluene mitochondrially encoded cytochrome c oxidase II Homo sapiens