Title : Reversible C-H Activation, Facile C-B/B-H Metathesis and Apparent Hydroboration Catalysis by a Dimethylxanthene-Based Frustrated Lewis Pair.

Pub. Date : 2018 Jul 20

PMID : 29786906






1 Functional Relationships(s)
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1 A dimethylxanthene-based phosphine/borane frustrated Lewis pair (FLP) is shown to effect reversible C-H activation, cleaving phenylacetylene, PhCCH, to give an equilibrium mixture of the free FLP and phosphonium acetylide in CD2 Cl2 solution at room temperature. Boranes CD2 molecule Homo sapiens