Title : Metathesis cleavage of an N[double bond, length as m-dash]N bond in benzo[c]cinnolines and azobenzenes by triply-bonded ditungsten complexes.

Pub. Date : 2018 Apr 10

PMID : 29441373






1 Functional Relationships(s)
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1 When azobenzene was used as the substrate, a trans to cis isomerization induced by blue-LED light was essential prior to the metathesis cleavage of the N[double bond, length as m-dash]N bond by the W[triple bond, length as m-dash]W bond of (Me2N)2(TfO)W[triple bond, length as m-dash]W(OTf)(NMe2)2 (6), affording the corresponding imido-bridged dinuclear tungsten complexes 7-9. tfo NME/NM23 nucleoside diphosphate kinase 2 Homo sapiens