Title : Hydrogen Electrooxidation in Ionic Liquids Catalyzed by the NTf2 Radical.

Pub. Date : 2017 Mar 9

PMID : 29071009






7 Functional Relationships(s)
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1 Hydrogen Electrooxidation in Ionic Liquids Catalyzed by the NTf2 Radical. Hydrogen nuclear transport factor 2 Homo sapiens
2 Hydrogen electrooxidation via a "hydrogen abstraction" mechanism in an aprotic ionic liquid 1-butyl-1-methylpyrrolidinium bis-(trifluoromethylsulfonyl) [Bmpy][NTf2] under anaerobic conditions was investigated using cyclic voltammetry and density functional theory (DFT). Hydrogen nuclear transport factor 2 Homo sapiens
3 Hydrogen electrooxidation via a "hydrogen abstraction" mechanism in an aprotic ionic liquid 1-butyl-1-methylpyrrolidinium bis-(trifluoromethylsulfonyl) [Bmpy][NTf2] under anaerobic conditions was investigated using cyclic voltammetry and density functional theory (DFT). Hydrogen nuclear transport factor 2 Homo sapiens
4 It is found that a platinum bound NTf2 radical (NTf2 ) formed by the oxidation of NTf2- at anodic potential can catalyze the oxidation of hydrogen and enhance its reaction rate. Hydrogen nuclear transport factor 2 Homo sapiens
5 It is found that a platinum bound NTf2 radical (NTf2 ) formed by the oxidation of NTf2- at anodic potential can catalyze the oxidation of hydrogen and enhance its reaction rate. Hydrogen nuclear transport factor 2 Homo sapiens
6 It is found that a platinum bound NTf2 radical (NTf2 ) formed by the oxidation of NTf2- at anodic potential can catalyze the oxidation of hydrogen and enhance its reaction rate. Hydrogen nuclear transport factor 2 Homo sapiens
7 Both experimental and theoretical studies (DFT) have supported a mechanism involving a NTf2 radical intermediate that catalyzes the hydrogen redox processes. Hydrogen nuclear transport factor 2 Homo sapiens