Title : Stereochemical Characterization of Polyketide Stereotriads Synthesized via Hydrogen-Mediated Asymmetric syn-Crotylation.

Pub. Date : 2017 Oct 20

PMID : 28960976






5 Functional Relationships(s)
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1 Stereochemical Characterization of Polyketide Stereotriads Synthesized via Hydrogen-Mediated Asymmetric syn-Crotylation. Hydrogen synemin Homo sapiens
2 The stereoselective access to stereotriads as important polyketide building blocks is reported on the basis of the Krische-type hydrogen-mediated syn-crotylation. Hydrogen synemin Homo sapiens
3 This extension of the burgeoning transfer hydrogen methodology gives divergent asymmetric access to anti,syn and syn,syn polyketide stereotriads from the same alpha-chiral starting material and avoids potentially epimerizable aldehyde intermediates. Hydrogen synemin Homo sapiens
4 This extension of the burgeoning transfer hydrogen methodology gives divergent asymmetric access to anti,syn and syn,syn polyketide stereotriads from the same alpha-chiral starting material and avoids potentially epimerizable aldehyde intermediates. Hydrogen synemin Homo sapiens
5 This extension of the burgeoning transfer hydrogen methodology gives divergent asymmetric access to anti,syn and syn,syn polyketide stereotriads from the same alpha-chiral starting material and avoids potentially epimerizable aldehyde intermediates. Hydrogen synemin Homo sapiens