Title : A hydrophilic inorganic framework based on a sandwich polyoxometalate: unusual chemoselectivity for aldehydes/ketones with in situ generated hydroxylamine.

Pub. Date : 2017 Sep 12

PMID : 28812076






1 Functional Relationships(s)
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1 The combination of [WZn3(H2O)2(ZnW9O34)2]12- and Co(ii) provides a synergistical catalytic way to promote oximation of aldehyde/ketone with in situ generated hydroxylamine that initially produces an oxime, which further either dehydrates into a nitrile or undergoes a Beckmann rearrangement to form an amide. Hydroxylamine mitochondrially encoded cytochrome c oxidase II Homo sapiens