Title : Acetic Acid Mediated Sulfonylation of Allenylphosphine Oxides: Divergent Synthesis of Bifunctionalized 1,3-Butadienes and Allenes.

Pub. Date : 2017 Jul 7

PMID : 28598618






1 Functional Relationships(s)
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1 This new methodology involves tandem (Ar)O-C(sp3) bond cleavage and C(sp2)/C(sp3)-SO2 formation toward divergent synthesis of sulfonyl- and phosphinyl-bifunctionalized 1,3-butadienes or allenes, depending on the substitution at the terminal carbon atoms of allenylphosphine oxides. 1,3-butadiene Sp2 transcription factor Homo sapiens