Title : Charge and Spin-State Characterization of Cobalt Bis(o-dioxolene) Valence Tautomers Using Co Kβ X-ray Emission and L-Edge X-ray Absorption Spectroscopies.

Pub. Date : 2017 Jan 17

PMID : 28035824






1 Functional Relationships(s)
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1 A comparison of their Kbeta XES spectra with the spectra of cobalt coordination complexes with known oxidation and spin states demonstrates that the low-temperature valence tautomer can be described as a low-spin CoIII configuration and the high-temperature valence tautomer as a high-spin CoII configuration. Cobalt mitochondrially encoded cytochrome c oxidase III Homo sapiens