Title : Molecular Mechanisms of Spin Crossover in the {Fe(pz)[Pt(CN)4]} Metal-Organic Framework upon Water Adsorption.

Pub. Date : 2016 May 18

PMID : 27149014






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1 The decrease of the spin-crossover temperature of {Fe(pz)[Pt(CN)4]} upon water adsorption predicted by the simulations is in agreement with the available experimental data and is traced back to the elongation of the bonds between the Fe(II) atoms and the organic linkers induced by interactions of the adsorbed water molecules with the framework. Platinum spindlin 1 Homo sapiens