Title : Semi-Crystalline Polar Polyethylene: Ester-Functionalized Linear Polyolefins Enabled by a Functional-Group-Tolerant, Cationic Nickel Catalyst.

Pub. Date : 2016 Jun 13

PMID : 27135297






2 Functional Relationships(s)
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1 A dibenzobarrelene-bridged, alpha-diimine Ni(II) catalyst (rac-3) was synthesized and shown to have exceptional behavior for the polymerization of ethylene. ethylene Rac family small GTPase 3 Homo sapiens
2 Catalyst rac-3 demonstrated living behavior at room temperature, produced linear polyethylene (Tm =135 C) at -20 C, and, most importantly, was able to copolymerize ethylene with the biorenewable polar monomer methyl 10-undecenoate to yield highly linear ester-functionalized polyethylene. ethylene Rac family small GTPase 3 Homo sapiens