Title : Unusual Formal [1+4] Annulation through Tandem P(NMe2 )3 -Mediated Cyclopropanation/Base-Catalyzed Cyclopropane Rearrangement: Facile Syntheses of Cyclopentenimines and Cyclopentenones.

Pub. Date : 2016 Apr 18

PMID : 26919274






2 Functional Relationships(s)
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1 Unusual Formal [1+4] Annulation through Tandem P(NMe2 )3 -Mediated Cyclopropanation/Base-Catalyzed Cyclopropane Rearrangement: Facile Syntheses of Cyclopentenimines and Cyclopentenones. cyclopropane NME/NM23 nucleoside diphosphate kinase 2 Homo sapiens
2 Mechanistic investigation implies that this reaction takes place through a P(NMe2 )3 -mediated cyclopropanation followed by a base-catalyzed cyclopropane rearrangement. cyclopropane NME/NM23 nucleoside diphosphate kinase 2 Homo sapiens