Title : The electrochemical oxidation of toluene catalysed by Co(II) in N-butyl-N-methylpyrrolidinium bis(trifluoromethylsulfonyl)imide.

Pub. Date : 2015 Dec 14

PMID : 26538114






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1 The electrochemical oxidation of toluene catalysed by Co(II) in N-butyl-N-methylpyrrolidinium bis(trifluoromethylsulfonyl)imide. Toluene mitochondrially encoded cytochrome c oxidase II Homo sapiens
2 The electrochemical oxidation of toluene in N-butyl-N-methylpyrrolidinium bis(trifluoromethylsulfonyl)imide ([bmpyr](+)[Ntf2](-)) was investigated by using cyclic voltammetry and galvanostatic electrolysis in the presence of Co(II) at a Pt disc working electrode. Toluene mitochondrially encoded cytochrome c oxidase II Homo sapiens
3 The diffusion coefficient values of Co(II) were found to increase from 0.38 x 10(-7) to 1.9 x 10(-7) cm(2) s(-1) as the temperature was increased from 25 C to 80 C. The CV peak current for toluene electro-oxidation increased by nearly 7 fold in the presence of Co(II) demonstrating a good catalytic effect. Toluene mitochondrially encoded cytochrome c oxidase II Homo sapiens
4 Co(II) catalysed galvanostatic electrolysis of toluene at room temperature has shown that benzaldehyde was formed along with a small quantity of 3-methyl-1-hexanol. Toluene mitochondrially encoded cytochrome c oxidase II Homo sapiens