Title : Restricting the ψ Torsion Angle Has Stereoelectronic Consequences on a Scissile Bond: An Electronic Structure Analysis.

Pub. Date : 2015 Sep 22

PMID : 26332921






1 Functional Relationships(s)
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1 Concomitant with the reduction in nN pi* delocalization energy, the sp(2) hybrid orbital of the carbonyl carbon becomes richer in p-character, suggesting the syn configuration causes the carbonyl carbon hybrid orbitals to adopt a geometry reminiscent of a tetrahedral-like intermediate. sp(2) synemin Homo sapiens