Title : Spin Crossover, Reversible Redox, and Supramolecular Interactions in 3d Complexes of 4-(4-Pyridyl)-2,5-dipyrazyl-pyridine.

Pub. Date : 2015 Jun 1

PMID : 25970648






2 Functional Relationships(s)
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1 These potentials are shifted to significantly higher potentials (by ~0.45 V) than the literature values for the corresponding Fe(II) and Co(II) complexes of the equivalent all-pyridine ligand, consistent with replacement of the two pyridine rings by two pyrazine rings significantly stabilizing the lower oxidation states. pyridine mitochondrially encoded cytochrome c oxidase II Homo sapiens
2 These potentials are shifted to significantly higher potentials (by ~0.45 V) than the literature values for the corresponding Fe(II) and Co(II) complexes of the equivalent all-pyridine ligand, consistent with replacement of the two pyridine rings by two pyrazine rings significantly stabilizing the lower oxidation states. pyridine mitochondrially encoded cytochrome c oxidase II Homo sapiens