Title : Mild P-P bond cleavage in the methyldiphosphenyl complex [Mo2Cp2(μ-PCy2)(μ-κ(2):κ(2)-P2Me)(CO)2] to give novel phosphide-bridged trinuclear derivatives.

Pub. Date : 2014 Oct 20

PMID : 25300937






1 Functional Relationships(s)
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1 However, these diphosphenyl complexes were unstable and decomposed at room temperature or under mild heating by the release of methylphosphinidene (PMe), to give the corresponding derivatives [Mo2MCp2(mu3-P)(mu-PCy2)(CO)2Ln] displaying trigonal-planar phosphide ligands, giving rise to strongly deshielded (31)P NMR resonances (deltaP ca. methylphosphinidene cystatin B Homo sapiens