Title : A general diversified synthesis of carbazoles and the first synthesis of karapinchamine A.

Pub. Date : 2014 Nov 3

PMID : 25256626






1 Functional Relationships(s)
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1 Highly selective 1,2-migration referring to the two substituents R(3) and R(4) (R(4) =H, alkyl, and aryl group) was observed: (1) In the presence of both H and alkyl groups, 1,2-hydrogen migration is exclusive; (2) in the presence of a methyl group (R(3) ), propyl, isopropyl, 4-methylphenyl, and 4-chlorophenyl groups (R(4) ) migrate exclusively. Hydrogen CD1d molecule Homo sapiens