Title : Synthesis of partially O-acetylated N-acetylneuraminic acid using regioselective silyl exchange technology.

Pub. Date : 2014 Oct 3

PMID : 25247390






1 Functional Relationships(s)
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1 Reaction of per-O-silylated Neu5Ac ester with AcOH and Ac2O in pyridine promotes regioselective silyl ether/acetate exchange in the following order: C4 (2 ) > C9 (1 ) > C8 (2 ) > C2 (anomeric). pyridine adenylate cyclase 2 Homo sapiens