Title : A pentanuclear lead(II) complex based on a strapped porphyrin with three different coordination modes.

Pub. Date : 2014 Oct 6

PMID : 25210805






2 Functional Relationships(s)
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1 We have previously described Pb(II) and Bi(III) bimetallic complexes with overhanging carboxylic acid strapped porphyrins in which one metal ion is bound to the N-core ("out-of-plane", OOP), whereas the second one is bound to the strap ("hanging-atop", HAT). Porphyrins serine/threonine kinase receptor associated protein Homo sapiens
2 Interestingly, investigations of the HAT metal coordination mode in a single strap porphyrin show that a HAT Pb(II) can also interact via intermolecular coordination bonds, allowing the self-assembly of two bimetallic complexes. Porphyrins serine/threonine kinase receptor associated protein Homo sapiens