Title : Selective ortho-hydroxylation-defluorination of 2-fluorophenolates with a bis(μ-oxo)dicopper(III) species.

Pub. Date : 2014 Sep 1

PMID : 25044926






1 Functional Relationships(s)
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1 The bis(mu-oxo)dicopper(III) species [Cu(III) 2 (mu-O)2 (m-XYL(MeAN) )](2+) (1) promotes the electrophilic ortho-hydroxylation-defluorination of 2-fluorophenolates to give the corresponding catechols, a reaction that is not accomplishable with a (eta(2) :eta(2) -O2 )dicopper(II) complex. Catechols adaptor related protein complex 1 subunit mu 2 Homo sapiens