Title : Regioselectivity in the Cu(I)-catalyzed [4 + 2]-cycloaddition of 2-nitrosopyridine with unsymmetrical dienes.

Pub. Date : 2014 Jun 20

PMID : 24853468






1 Functional Relationships(s)
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1 The regioselectivity of the pentadiene/PyrNO reaction is improved markedly (90:10 dist/prox) when catalyzed by Cu(CH3CN)4(+); (diimine)2Cu(+) catalysts increase selectivity for the proximal product (55-65%). Alkadienes pyruvate dehydrogenase complex component X Homo sapiens