Title : Cobalt-catalyzed methoxycarbonylation of substituted dichlorobenzenes as an example of a facile radical anion nucleophilic substitution in chloroarenes.

Pub. Date : 2014 May 6

PMID : 24806583






1 Functional Relationships(s)
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1 The results demonstrate that the reaction is potentially useful as it proceeds under very mild conditions (t = 62 C, PCO = 1 bar) and converts aryl chlorides to far more valuable products (especially ortho-substituted benzoic acids and esters) in high yields. aryl chlorides PCOS1 Homo sapiens