Title : Fluoride-bridged {Gd(III)3M(III)2} (M = Cr, Fe, Ga) molecular magnetic refrigerants.

Pub. Date : 2014 Feb 24

PMID : 24574031






1 Functional Relationships(s)
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1 The reaction of fac-[M(III)F3(Me3tacn)] x H2O with Gd(NO3)3 5H2O affords a series of fluoride-bridged, trigonal bipyramidal {Gd(III)3M(III)2} (M = Cr (1), Fe (2), Ga (3)) complexes without signs of concomitant GdF3 formation, thereby demonstrating the applicability even of labile fluoride-complexes as precursors for 3d-4f systems. Water FA complementation group C Homo sapiens