Title : Formation, expansion, and interconversion of metallarings in a sulfur-bridged Au(I) Co(III) coordination system.

Pub. Date : 2014 Feb 10

PMID : 24403126






1 Functional Relationships(s)
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1 Treatment of 2 with [Au2 (dppe)2 ](2+) (dppe=1,2-bis(diphenylphosphino)ethane) leads to the formation of [Au4 Co2 (dppe)2 (D-nmp)4 ](2+) (3(2+) ), which consists of an 18-membered Au(I) 4 Co(III) 2 metallaring that accommodates a tetrahedral anion (BF4 (-) , ClO4 (-) , ReO4 (-) ). perrhenate complement C2 Homo sapiens