Title : Fe-catalyzed one-pot oxidative cleavage of unsaturated fatty acids into aldehydes with hydrogen peroxide and sodium periodate.

Pub. Date : 2013 Oct 25

PMID : 24105732






1 Functional Relationships(s)
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1 A one-pot method has been developed for the oxidative cleavage of internal alkenes into aldehydes by using 0.5 mol% of the nonheme iron complex [Fe(OTf)2(mix-bpbp)] (bpbp=N,N"-bis(2-picolyl)-2,2"-bipyrrolidine) as catalyst and 1.5 equivalents of hydrogen peroxide and 1 equivalent of sodium periodate as oxidants. Iron POU class 2 homeobox 2 Homo sapiens