Title : Mechanistic aspects of metal valence change in SalenCo(III)OAc-catalyzed hydrolytic kinetic resolution of racemic epoxides.

Pub. Date : 2013 May 17

PMID : 23631353






1 Functional Relationships(s)
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1 Continuous determination of transient cationic species in ESI-MS positive mode in conjunction with UV-vis spectroscopic studies at various time points provides evidence that a certain amount of SalenCo(III)OAc molecules were reduced to the corresponding Co(II) derivatives in the HKR of racemic propylene oxide or styrene oxide. styrene oxide mitochondrially encoded cytochrome c oxidase III Homo sapiens