Title : Identification of a nonanuclear {Co(II)9} polyoxometalate cluster as a homogeneous catalyst for water oxidation.

Pub. Date : 2012 Nov 5

PMID : 23078372






1 Functional Relationships(s)
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1 We carried out our experiments with an excess of 2,2"-bipyridyl as the chelating agent for free aqueous Co(II) ions, in order to avoid the formation of a cobalt oxide film on the electrode, as observed for other polyoxometalate catalysts. 2,2'-Dipyridyl mitochondrially encoded cytochrome c oxidase II Homo sapiens