Title : The "missing link": the gas-phase generation of platinum-methylidyne clusters Pt(n)CH+ (n=1, 2) and their reactions with hydrocarbons and ammonia.

Pub. Date : 2011 Oct 10

PMID : 21898612






1 Functional Relationships(s)
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1 Finally, in the ion-molecule reactions with ammonia, both platinum complexes give rise to proton transfer to produce NH(4)(+); however, only the encounter complex generated with PtCH(+) undergoes efficient dehydrogenation of the substrate, and the rather minor formation of CNH(4)(+) indicates that C-N bond coupling is inefficient. nh(4) patched 1 Homo sapiens