Title : Comparison of Structurally-Related Alkoxide, Amine, and Thiolate-Ligated M (M= Fe, Co) Complexes: the Influence of Thiolates on the Properties of Biologically Relevant Metal Complexes.

Pub. Date : 2008 Mar 3

PMID : 21731109






1 Functional Relationships(s)
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1 Redox potentials for structurally-related Co(II) complexes are shown to be cathodically-shifted relative to their Fe(II) analogues, making them ineffective reducing agents for substrates such as superoxide. Superoxides mitochondrially encoded cytochrome c oxidase II Homo sapiens