Title : Effective 1,5-, 1,6- and 1,7-remote stereocontrol in reactions of alkoxy- and hydroxy-substituted allylstannanes with aldehydes.

Pub. Date : 2011 May 21

PMID : 21472165






1 Functional Relationships(s)
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1 Alk-2-enylstannanes with 4-, 5- and 6-alkoxy- or -hydroxy-substituents are transmetallated stereoselectively with tin(iv) halides to generate allyltin trihalides which react with aldehydes to give (Z)-alk-3-enols with useful levels of 1,5-, 1,6- and 1,7-stereocontrol. 1,5-, 1,6- and 1,7-stereocontrol activin A receptor type 1 Homo sapiens