Title : Effect of buffer general acid-base catalysis on the stereoselectivity of ester and thioester H/D exchange in D2O.

Pub. Date : 2011 Apr 6

PMID : 21384891






1 Functional Relationships(s)
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1 It is likely that hydrogen bonding in the enolate-buffer acid encounter complex is an important stereochemical determinant in producing a greater amount of the 2R*, 3S* diastereomer (the syn product). enolate synemin Homo sapiens