Title : Iron catalyzed competitive olefin oxidation and ipso-hydroxylation of benzoic acids: further evidence for an Fe(V)═O oxidant.

Pub. Date : 2010 Oct 18

PMID : 20866083






2 Functional Relationships(s)
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1 It is proposed that benzoic acid and water compete for the available sixth site on the [(TPA)Fe(III)(OOH)] intermediate, which undergoes O-O bond heterolysis to form, respectively, the Fe(V)(O)(O(2)CAr) and Fe(V)(O)(OH) oxidants that determine the product outcome. Water FEV transcription factor, ETS family member Homo sapiens
2 It is proposed that benzoic acid and water compete for the available sixth site on the [(TPA)Fe(III)(OOH)] intermediate, which undergoes O-O bond heterolysis to form, respectively, the Fe(V)(O)(O(2)CAr) and Fe(V)(O)(OH) oxidants that determine the product outcome. Water FEV transcription factor, ETS family member Homo sapiens