Title : Gold catalysis: tandem reactions of diyne-diols and external nucleophiles as an easy access to tricyclic cage-like structures.

Pub. Date : 2010 Aug 23

PMID : 20632335






1 Functional Relationships(s)
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1 Subjection of the syn diastereomers to NAC-gold catalysts (NAC=nitrogen acyclic carbene) in the presence of external nucleophiles such as water or anilines provided substituted and highly rigid heterocyclic cages. Nitrogen synemin Homo sapiens