Title : Preparation of syn-tertiary homoallylic alcohols utilizing allenyltitanocenes generated by reductive titanation of gamma-trimethylsilylpropargylic carbonates.

Pub. Date : 2010 May 7

PMID : 20355742






1 Functional Relationships(s)
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1 syn-Tertiary homoallylic alcohols were obtained by the reaction of alpha-silylallenyltitanocenes generated by the reductive titanation of gamma-silylpropargylic carbonates with Cp(2)Ti[P(OEt)(3)](2) with ketones and following desilylation and partial hydrogenation. Ketones synemin Homo sapiens