Title : Effect of hydroxyl and amino groups on electrochemiluminescence activity of tertiary amines at low tris(2,2'-bipyridyl)ruthenium(II) concentrations.

Pub. Date : 2010 Apr 15

PMID : 20188885






2 Functional Relationships(s)
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1 Surprisingly, ECL intensities of monoamines, such as 2-(dibutylamino)ethanol and N-butyldiethanolamine, are much stronger than that of diamines including N,N,N",N"-tetrakis-(2-hydroxyethyl)-ethylenediamine and N,N,N",N"-tetrakis-(2-hydroxypropyl)ethlenediamine. Diamines C-C motif chemokine ligand 21 Homo sapiens
2 The striking contrast between ECL signals of the investigated monoamines and diamines may result from more significant side reactions of diamines, such as the intramolecular side reactions between oxidative amine cation radicals and reductive amine free radicals. Diamines C-C motif chemokine ligand 21 Homo sapiens