Title : Reaction of hydrogen peroxide with coordinated superoxide in [(NH3)5CoIII(micro-O2)CoIII(NH3)5]5+: a mechanistic study.

Pub. Date : 2009 Jul 28

PMID : 19587989






3 Functional Relationships(s)
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1 Reaction of hydrogen peroxide with coordinated superoxide in [(NH3)5CoIII(micro-O2)CoIII(NH3)5]5+: a mechanistic study. Superoxides mitochondrially encoded cytochrome c oxidase III Homo sapiens
2 In aqueous acetate buffer media, hydrogen peroxide reduces the bridging superoxide in [(NH3)5CoIII(micro-O2)CoIII(NH3)5]5+ (1) to the corresponding peroxide in the complex, [(NH3)5CoIII(micro-O2H)CoIII(NH2)(NH3)4]4+ (2), itself being oxidized to HO2*. Superoxides mitochondrially encoded cytochrome c oxidase III Homo sapiens
3 In aqueous acetate buffer media, hydrogen peroxide reduces the bridging superoxide in [(NH3)5CoIII(micro-O2)CoIII(NH3)5]5+ (1) to the corresponding peroxide in the complex, [(NH3)5CoIII(micro-O2H)CoIII(NH2)(NH3)4]4+ (2), itself being oxidized to HO2*. Superoxides mitochondrially encoded cytochrome c oxidase III Homo sapiens