Title : A new approach to 3-hydroxyprolinol derivatives by samarium diiodide-mediated reductive coupling of chiral nitrone with carbonyl compounds.

Pub. Date : 2009 Jul 21

PMID : 19582307






1 Functional Relationships(s)
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1 The reductive hydroxyalkylation of nitrone 10 with ketones and aromatic aldehydes is highly diastereoselective in establishing the C-2 chiral center of the pyrrolidine ring. Ketones complement C2 Homo sapiens